The Intel® Wireless Dock Manager Software was designed to be used as a Windows* App, using the graphical interface. It was not planned as a command line application, allowing options and objects in the command prompt. Currently, it is not possible to connect to a specific Docking station by typing a single command.
Please let us know if these computers are for personal use, or for business purposes. Also, let us know the reason why you would like to use CLI instead of the GUI.