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Should work fine as long as you reconfigure everything as is.
However, there are possibly easier/better ways of testing for your consideration:
1) Just install the SSD as another storage device and redirect your application output/temp files to the SSD. You can also use a 3rd party program called Steam Mover which will create junction points to the SSD.
2) Use the Intel Data Migration tool and apply an image of the RAID1 to the SSD. This way you don't have to reinstall anything. The other limitation of this is the used space on the partition cannot be greater than the SSD size.