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Thank you for posting in the Intel® communities.
Regarding to the Intel® Optane™ Memory, it is supported only in Windows* 10 64-bit, so it won’t work properly on a VMware platform.
Regarding to the questions about VMware* vSphere Hypervisor, I don’t have the answers for you as those questions go beyond of our support scope, however I recommend you to check the following VMware* site where you will find detail information and more appropriate support for your inquiries: vSphere, Training & Technical Documentation
I hope that I have clarified your concern about the Intel® Optane™ Memory. If there is anything else I can help you with about the module, feel free to ask.
Have a nice day.