Thank you for joining the Intel® Community. I can sure help with your inquiry.
Intel Unite® app works with plugins, so there must be a specific plugin for the app in order to be used with Intel Unite®. For Skype there is a plugin, and you can find all the information on how to use it here: http://www.intel.com/content/www/us/en/support/software/000022054.html, but unfortunately for Outlook there is no plugin.
I would like to share with you some helpful links;
Components and System Requirements for the Intel® Unite™ app: http://www.intel.com/content/www/us/en/support/software/software-applications/000017827.html
If you have more questions, please let us know.
Majed445, I just wanted to let you know that there is actually a plugin for Microsoft Outlook. You will be able to find it here: Download Intel Unite® App. Download the package and then look for the "Intel Unite Add-in for Microsoft Outlook.mui.msi" file. Also, you can get more information about this plugin in the Appendix A: Intel Unite Plugin for Microsoft* Outlook in the following guide: User Guide for the Intel Unite® app.