I ultimately did find the table of max array sizes on Intel's website, and PeterUK is correct about the 2TB limit on an ICH7R. I bought a new motherboard with an ICH10R (aka Series 4) chipset, and I was able to create the 4.5TB array. Note that I also had to install a 64-bit version of Windows, since 32-bit versions have a 2TB per disk limit.
Hopefully Google will index this entry so others can find it.