Intel® ICH7R South Bridge:
*4 x Serial ATA I/II 3.0Gb/s with Intel® Matrix Storage
Technology with RAID 0, 1, 5, 10 support
in Intel Matrix Storage Manager option ROM utility (Ctrl-I):
RAID 5
3x250Gb =~500 it's ok
3x1Tb = ~1800 GB
4x1Tb = ~ 764,5 GB 
Is this a limitation of the controller? or BIOS? or motherboard?
ASUS P5LD2-V - + 4x ST31000524NS